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Manganese and iron are contained in many groundwater deposits. Without treatment, these substances can cause serious technical problems in water pipes. The elements manganese and iron are present in dissolved form as iron (II) and manganese (II) ions in oxygen-poor waters such as groundwater. Insoluble manganese (IV) and iron (III) oxides are formed by oxygen or biological oxidation. These form reddish-brown (iron) or black (manganese) precipitates, which can lead to turbidity and coloration of the water and deposits in pipelines. These deposits can be reinforced by manganese and iron bacteria. The consequences would be undesired pressure loss in the pipe network and biofilm formation. In addition, iron and manganese worsen the taste of the water and also lead to discoloration of teeth. It is therefore important to keep the concentration of iron and manganese in pipe networks as low as possible. The Drinking Water Regulation stipulates a limit value of 0.2 mg-L-1 for iron and 0.05 mg-L-1 for manganese.

For the removal of iron and manganese SFC Umwelttechnik GmbH offers a highly innovative water treatment process – a combination of the processes C-ION – advanced oxidation with non-thermal plasma (NTP, oxidation of manganese and organic compositions) and C-MEM™ – ultrafiltration membrane technology (complete separation of precipitates and bacteria / viruses > 0.02 µm). This process combination makes it possible to remove manganese and iron from well water and to treat it to drinking water quality.

As already mentioned above, the limit values of iron and manganese according to the Drinking Water Regulation 304/2001 are 0.2 mg-l-1 and 0.05 mg-l-1 respectively. The values below show that the limit values can be far below the limits after treatment with non-thermal plasma.

 

Fe Mn
Unit [mg·l-1] [mg·l-1]
Raw water 0.340 0.230
Sample after 60 min aeration with ambient air 0.034 0.22
Sample after 60 min aeration with NTP 0.031 0.020
Sample after 30 min aeration with NTP 0.010 0.021
Sample after 15 min aeration with NTP 0.034 0.016
Sample after 10 min aeration with NTP 0.034 0.016
Sample after 5 min aeration with NTP 0.034 0.024

 

Advantages

  • avoidance of turbidity and colouring and improvement of the taste of the water
  • prevention of precipitation, biofilm formation and overgrowth of pipelines
  • small space requirement
  • modularly expandable
  • simple installation and commissioning
  • periodic operation possible
  • additional complete removal of particulate solids, bacteria and viruses (membrane barrier)
  • additional reduction of other organic pollutants (NH4, COD, pesticides, herbicides)
  • additional reduction of organic deposits
  • long life of equipment, cost effective and easy to replace
  • low energy requirement
  • no additional chemicals necessary
  • robust process, no fine mechanical parts

The process combination of advanced oxidation with non-thermal plasma C-ION and ultrafiltration
C-MEMTM successfully removes iron and manganese contamination in water of several milligrams / liter within a few minutes treatment time to non-detectability.

 

Pilot Test Fe-Mn-Removal at 0.5 kHz and 36 Watt_final

 

Unique Features:

We have learned from the deficiencies of other iron and manganese removal technologies and have refined these technologies.

The following features prove this and hence clearly speak for the process combination of C-ION and C-MEM:

 

No additional oxidation or precipitation chemicals

 Chemikalien

thus lower operating costs, no handling of hazardous chemicals, no reaction by-products

 

Few components, easy installation and simple operation

C-ION Turbine

thus low space requirement, installation in existing tanks possible and low maintenance costs

 

Additional removal of bacteria, viruses and organic pollutants (pesticides, herbicides)

Pestizide

because these also represent a high health risk for humans and can be removed without additional effort with this process combination